Coke

Summary: Coke is a form of carbon produced by heating coal in the absence of air. In the blast furnace, coke serves two purposes: as a fuel (burns to produce heat) and as the source of the reducing agent carbon monoxide. Tags: igcse chemistry definition metals extraction Created: 2026-07-14 Last Updated: 2026-07-23


Coke is a porous, high-carbon solid produced by heating coal in the absence of air (destructive distillation). It is almost pure carbon and is a vital raw material in the blast furnace for iron extraction.

Role in the Blast Furnace

Coke serves two essential functions:

1. Fuel — Produces Heat

C(s) + O₂(g) → CO₂(g)

Hot air is blasted into the furnace from the bottom. Coke burns in this air, releasing large amounts of heat (the reaction is highly exothermic). This heat:

  • Maintains the furnace temperature at ~1500°C
  • Keeps the iron and slag in molten state

2. Source of Reducing Agent

CO₂(g) + C(s) → 2CO(g)

The carbon dioxide produced from burning coke reacts with more hot coke to form carbon monoxide (CO) — the actual reducing agent that converts iron oxide to iron:

Fe₂O₃(s) + 3CO(g) → 2Fe(l) + 3CO₂(g)

Why Coke?

  • Cheap and abundant — produced from coal
  • High carbon content → efficient fuel and reducing agent
  • Porous structure → allows gases to flow through
  • Provides both heat AND reducing agent in one material

Key Facts

  • Coke = almost pure carbon from heating coal without air
  • Fuel: C + O₂ → CO₂ (provides heat)
  • Reducing agent source: CO₂ + C → 2CO
  • CO reduces iron oxide: Fe₂O₃ + 3CO → 2Fe + 3CO₂
  • Essential raw material for the blast furnace
  • Added at the top of the furnace along with hematite and limestone

See Also


This is a key term definition page — part of the IGCSE Chemistry (0620/0971) keyword glossary.