Cambridge IGCSE Chemistry 0620 Syllabus (2023-2025) Answers
→ Back to Syllabus Questions · Full Syllabus
Summary: Complete point-form answers to the Cambridge IGCSE Chemistry 0620 syllabus (2023-2025). Keywords are linked to their dedicated study pages for exam-focused revision. Tags: answers igcse chemistry syllabus revision Created: 2026-08-06
1 States of Matter
1.1 Solids, Liquids and Gases
Core:
-
Structures in terms of particle separation, arrangement and motion:
- Solid:
- Separation: tightly packed together
- Arrangement: regular lattice structure
- Motion: vibrate about fixed positions
- Liquid:
- Separation: close together
- Arrangement: random arrangement
- Motion: slide past one another
- Gas:
- Separation: far apart
- Arrangement: random arrangement
- Motion: move rapidly and randomly in all directions
- Solid:
-
Changes of state: melting, boiling, evaporating, freezing and condensing:
- Melting: Solid → Liquid when heat energy is added
- Boiling: Liquid → Gas at a specific temperature throughout the liquid
- Evaporation: Liquid → Gas below the boiling point, occurring only at the surface
- Freezing: Liquid → Solid when heat energy is removed
- Condensation: Gas → Liquid when heat energy is removed
-
Effects of temperature and pressure on the volume of a gas:
- Temperature: increasing temperature increases volume (at constant pressure)
- Pressure: increasing pressure decreases volume (at constant temperature)
Supplement:
-
Changes of state in terms of kinetic particle theory, including heating and cooling curves:
- As temperature increases, particles gain kinetic energy and move faster
- During Melting or Boiling, thermal energy overcomes intermolecular forces rather than increasing particle speed → temperature stays constant → horizontal plateaus on heating curves
- During Freezing or Condensation, energy is released as attractions form → constant temperature
- Heating Curve shows temperature vs time with flat sections at melting/boiling points
- Cooling Curve shows the reverse — flat sections at condensation/freezing points
-
Effects of temperature and pressure on gas volume via kinetic particle theory:
- Temperature: heating gives gas particles more kinetic energy → move faster → collide with container walls with greater force and frequency → volume increases to maintain constant pressure
- Pressure: increasing external pressure forces gas particles closer together → reduces space between them → decreases volume
1.2 Diffusion
Core:
- Diffusion in terms of kinetic particle theory:
- Diffusion: net movement of particles from a region of higher concentration to a region of lower concentration down a concentration gradient
- Caused by continuous, random movement and collisions of fluid particles
Supplement:
- Effect of relative molecular mass on the rate of diffusion of gases:
- Gas molecules with a lower relative molecular mass (Mᵣ) diffuse faster than those with a higher Mᵣ at the same temperature
- Lighter molecules have higher average speed at a given temperature
2 Atoms, Elements and Compounds
2.1 Elements, Compounds and Mixtures
Core:
- Differences between elements, compounds and mixtures:
- Element: pure substance of only one type of atom; cannot be broken down by chemical means
- Compound: pure substance of two or more different elements chemically combined in fixed proportions
- Mixture: two or more substances physically mixed without chemical bonding; components retain individual properties; can be separated by physical methods
2.2 Atomic Structure and the Periodic Table
Core:
-
Structure of the atom:
-
Relative charges and masses of subatomic particles:
-
- Number of protons in the nucleus of an atom
- Determines the identity of the element
- In a neutral atom, equals the number of electrons
-
- Total number of protons + neutrons in the nucleus
- Mass number = atomic number + number of neutrons
-
Electronic configuration of elements and ions (proton numbers 1–20):
- Electrons fill shells in order: 2, 8, 8, 2
- e.g. Sodium = 2,8,1; Aluminium = 2,8,3; Calcium = 2,8,8,2
- Ions gain/lose electrons to achieve noble gas configuration (full outer shell)
-
Periodic Table trends:
- (a) Group VIII (Noble Gases): have a full outer shell → unreactive
- (b) Groups I to VII: number of outer shell electrons = group number
- (c) Period number: number of occupied electron shells = period number
2.3 Isotopes
Core:
-
Isotopes definition:
- Different atoms of the same element with the same number of protons but different numbers of neutrons
- Same atomic number, different mass number
-
- Written as ᴬᶻX where A = mass number, Z = atomic number
- e.g. ¹²₆C means 6 protons, 6 neutrons; ³⁵₁₇Cl⁻ means 17 protons, 18 neutrons, 18 electrons
Supplement:
-
Isotopes — same chemical properties:
- Isotopes of the same element have the same chemical properties
- Reason: same number of electrons → same electronic configuration
- Physical properties (e.g. density, rate of diffusion) may differ due to different masses
-
Relative atomic mass calculation:
- Aᵣ = Σ (isotopic mass × % abundance) ÷ 100
- Takes into account all naturally occurring isotopes and their relative abundances
- e.g. for chlorine: Aᵣ = (35 × 75 + 37 × 25) ÷ 100 = 35.5
2.4 Ions and Ionic Bonds
Core:
-
Formation of positive ions (cations) and negative ions (anions):
- Cations: formed when an atom loses one or more electrons → positive charge
- Metals (Groups I–III) tend to lose electrons
- e.g. Na → Na⁺ + e⁻, Mg → Mg²⁺ + 2e⁻
- Anions: formed when an atom gains one or more electrons → negative charge
- Non-metals (Groups V–VII) tend to gain electrons
- e.g. Cl + e⁻ → Cl⁻, O + 2e⁻ → O²⁻
- Cations: formed when an atom loses one or more electrons → positive charge
-
Ionic bond definition:
- Strong electrostatic attraction between oppositely charged ions
- Formed by electron transfer from a metal to a non-metal
-
Formation of ionic bonds between Group I and Group VII elements:
- Group I metal loses 1 electron → 1+ ion
- Group VII non-metal gains 1 electron → 1− ion
- Use dot-and-cross diagrams:
- e.g. NaCl: Na donates 1 electron to Cl → Na⁺ and Cl⁻
- Show outer electrons as dots (one element) and crosses (other element)
-
Properties of ionic compounds:
- (a) High melting and boiling points (strong electrostatic forces in the giant lattice)
- (b) Good electrical conductivity when aqueous or molten (ions are free to move); poor conductivity when solid (ions held in fixed positions)
Supplement:
-
Giant ionic lattice structure:
- Regular arrangement of alternating positive and negative ions
- e.g. NaCl forms a cubic lattice with each Na⁺ surrounded by 6 Cl⁻ (and vice versa)
- Held together by strong electrostatic forces in all directions
-
Formation of ionic bonds between metals and non-metals:
- Metal atoms lose electrons → cations
- Non-metal atoms gain electrons → anions
- Use dot-and-cross diagrams:
- e.g. MgO: Mg loses 2e⁻ → Mg²⁺, O gains 2e⁻ → O²⁻
- e.g. CaCl₂: Ca loses 2e⁻ → Ca²⁺, two Cl atoms each gain 1e⁻ → 2Cl⁻
-
Explain properties of ionic compounds in terms of structure and bonding:
- (a) boiling points: strong electrostatic forces between oppositely charged ions in the giant lattice require large amounts of energy to overcome
- (b) Good conductivity when aqueous/molten: ions are free to move and carry charge; poor conductivity when solid: ions locked in fixed lattice positions, cannot move
2.5 Simple Molecules and Covalent Bonds
Core:
-
Covalent bond definition:
- Formed when a pair of electrons is shared between two atoms
- Leads to noble gas electronic configurations (full outer shells)
- Occurs between non-metal atoms
-
Formation of covalent bonds in simple molecules:
- Using dot-and-cross diagrams:
- H₂: H—H (single bond, each H shares 1 electron → 2 in outer shell)
- Cl₂: Cl—Cl (single bond, each Cl shares 1 electron → 8 in outer shell)
- H₂O: H—O—H (two single bonds, O shares 2 electrons → 8, each H gets 2)
- CH₄: C with 4 single bonds to 4 H atoms (C shares 4 electrons → 8)
- NH₃: N with 3 single bonds to 3 H atoms + 1 lone pair
- HCl: H—Cl (single bond)
-
Properties of simple molecular compounds:
- (a) Low melting and boiling points (weak intermolecular forces)
- (b) Poor electrical conductivity (no ions or free electrons)
Supplement:
-
Formation of covalent bonds in more simple molecules:
-
Explain properties of simple molecular compounds in terms of structure and bonding:
- (a) boiling points: only weak intermolecular forces (not the strong covalent bonds) need to be overcome; small molecules have small intermolecular forces → little energy needed
- (b) Poor electrical conductivity: molecules are neutral overall; no ions or free electrons to carry charge
2.6 Giant Covalent Structures
Core:
-
Giant covalent structures of graphite and diamond:
- Diamond:
- Each carbon atom bonded to 4 other carbon atoms by strong covalent bonds
- Tetrahedral arrangement → rigid 3D giant lattice
- All 4 outer-shell electrons used in bonding → no free electrons
- Graphite:
- Each carbon atom bonded to 3 other carbon atoms in flat hexagonal layers
- 4th outer electron is delocalised → free to move between layers
- Layers held together by weak intermolecular forces → can slide
- Diamond:
-
Relate structures of graphite and diamond to their uses:
- (a) Graphite:
- As a Lubricant: layers slide over each other due to weak intermolecular forces between layers
- As an Electrode: delocalised electrons can move and carry charge → conducts electricity
- (b) Diamond:
- In cutting tools: extremely hard (each C atom held by 4 strong covalent bonds in rigid 3D tetrahedral lattice)
- (a) Graphite:
Supplement:
-
Giant covalent structure of silicon(IV) oxide, SiO₂:
- Similar to diamond: each Si atom bonded to 4 O atoms, each O bonded to 2 Si atoms
- Forms a continuous 3D tetrahedral giant lattice
- Overall formula SiO₂ (not SiO₂ molecules — the formula represents the ratio)
-
Similarity in properties between diamond and silicon(IV) oxide:
- Both have boiling points: all atoms held by strong covalent bonds throughout the giant structure
- Both are very hard: strong covalent bonds in 3D tetrahedral network resist deformation
- Both are electrical insulators: no free electrons (all electrons locked in bonds)
2.7 Metallic Bonding
Supplement:
-
Metallic bonding description:
- Electrostatic attraction between:
- Positive metal ions arranged in a giant metallic lattice
- A ‘sea’ of delocalised electrons (outer-shell electrons free to move throughout the structure)
- Metallic bond is the attraction between positive ion cores and the delocalised electron sea
- Electrostatic attraction between:
-
Explain properties of metals in terms of structure and bonding:
- (a) Good electrical conductivity: delocalised electrons are free to move throughout the metallic lattice and carry charge → conduct electricity and heat
- (b) Malleability and ductility: layers of ions in the giant metallic lattice can slide over each other without breaking the metallic bond; the delocalised electrons move with the ions and continue to hold them together → metal can be hammered into shapes (malleable) or drawn into wires (ductile)
3 Stoichiometry
3.1 Formulae
Core:
-
Formulae of elements and compounds in the subject content:
-
- Number and type of different atoms in one molecule
- e.g. C₂H₆ has 2 carbon atoms and 6 hydrogen atoms in one molecule
-
Deduce formula from diagram/model:
- Count number of each type of atom present
- Write as ratio → simplify if needed
- e.g. model showing 2 H and 1 O → H₂O